Initiation and propagation processes in thermally initiated solid‐state polymerization of sodium acrylate have been studied. The kinetics of initiation, followed with the electron spin resonance technique, leads to an activation energy E of 28.8 kcal/mol, which is attributed to the formation of dimeric radicals. The activation energy of 16 ± 1 kcal/mol obtained for the solid‐state polymerization of sodium acrylate by chemical analysis and differential scanning calorimetry has been attributed to the propagation process.
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Verneker et al. (1983) studied this question.
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