A new method is given for the preparation of aromatic isothiocyanates from the corresponding dithiocarbamates. The latter compounds are converted into S‐(carboxymethyl) ‐dithiocarbamates, which spontaneously decompose at pH 7 in the presence of certain heavy metal ions to yield isothiocyanates. The reaction mechanism is discussed.
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Pluygers et al. (1955) studied this question.
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