Three luminescence transitions in the 476 nm excited spectrum of Cs2NaTmCl6 between 7200–4100cm-1 are assigned to the 3 H 4 → 3 F 4, 3 H 5 and 3 F 4 → 3 H 6 transitions of TmCl3- 6. A crystal field analysis of the energy levels of this anion is given.
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Peter A. Tanner (1985) studied this question.
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