⌘+K

Pulse Explore Communities Researchers Journals

Home Communities Explore

October 30, 2006Chemical Communications

Models for the reactive states of homocuprates: syntheses, structures and reactivities of [Cu 2 Li 2 Mes 4 ] and [Cu 3 LiMes 4 ]

Robert P. Davies Stefan Hornauer Andrew J. P. White

View at Publisher

Ask AI

Bookmark

Share

Abstract

The synthesis and characterisation of two novel tetranuclear and thermally-stable lithium arylcuprates, [Cu(2)Li(2)Mes(4)] and [Cu(3)LiMes(4)], are reported and [Cu(3)LiMes(4)] is shown to be a highly active promoter for the 1,4-addition of organolithiums to enones.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Davies et al. (2006) studied this question.

synapsesocial.com/papers/6aa30bb59641e5d546c07c93 https://doi.org/10.1039/b612554a

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Synthesis and Structure of a Dimeric Lithium Diphenylcuprate: [{Li(OEt)<sub>2</sub>}(CuPh<sub>2</sub>)]<sub>2</sub>Original Research · 1990 · 64 citations
2Isolation and first structural characterization of dimethyl sulfide solvates of phenyllithium, phenylcopper, and lower and higher order lithium phenylcuprate reagentsOriginal Research · 1990 · 118 citations
3Crystal structure of the neutral diarylcuprate Cu2Li2(C6H4CH2NMe2-2)4: the asymmetric bonding configuration of organo groups bridging copper and lithiumOriginal Research · 1985 · 92 citations
4The Relation between Ion Pair Structures and Reactivities of Lithium CupratesOriginal Research · 2000 · 109 citations
5σ-Carbon versus π-Arene Interactions in the Solid-State Structures of Trimeric and Dimeric Copper Aryls (CuAr)n (n = 3, Ar = 2,6-Ph2C6H3; n = 2, Ar = 2,6-Mes2C6H3)Original Research · 1998 · 72 citations

More related papers

Isolation and x-ray crystal structures of the mononuclear cuprates [CuMe2]-, [CuPh2]-, and [Cu(Br)CH(SiMe3)2]-1985
Isolation and x-ray crystal structure of the cuprate complex decaethoxydichlorotetralithium bis(hexaphenyldilithiumtricuprate) ([Li2Cu3Ph6]2[Li4Cl2(Et2O)10]): the first x-ray structural characterization of an anionic organocopper-lithium cluster1984
Isolation and crystal and molecular structure of a rare example of a mononuclear organo-cuprate1983

More from Chemical Communications

Light-activated thiomaleimide crosslinking stabilizes collagen mimetic peptide triple helixThu,
Macrocyclic stibine-bridged [1.1.1] and [1.1.1.1] ferrocenophanesThu,