The scope and limitation of an iridium‐catalysed H/D exchange reaction has been investigated. Our results suggest a general mechanism for specific labelling at aromatic and non‐aromatic double bonds by D2O if an electron‐donating group is in a 1,4‐relation with the carbon where the H/D exchange takes place. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
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Krüger et al. (2005) studied this question.
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