Microstructure and corrosion study of porous Mg–Zn–Ca alloy in simulated body fluid

Magnesium alloys had been considered as promising biomedical devices due to their biocompatibility and biodegradability. In this present work, microstructure and corrosion properties of Mg–Zn–Ca–CaCO 3 porous magnesium alloy were examined. Porous metals were fabricated through powder metallurgy process with CaCO 3 addition as a foaming agent. CaCO 3 content was varied (1, 5, and 10%wt) followed by sintering process in 650 °C in Argon atmosphere for 10 and 15 h. The microstructure of the resulted alloys was analyzed by scanning electron microscopy (SEM) equipped with energy dispersive spectrometry data (EDS). Further, to examine corrosion properties, electrochemical test were conducted using G750 Gamry Instrument in accordance with ASTM standard G5-94 in simulated body fluid (Hank’s solution). As it was predicted, increasing content of foaming agent was in line with the increasing of pore formation. The electrochemical testing indicated corrosion rate would increase along with the increasing of foaming agent. The porous Mg–Zn–Ca alloy which has more porosity and connecting area will corrode much faster because it can transport the solution containing chloride ion which accelerated the chemical reaction. Highest corrosion resistance was given by Mg–Zn–Ca–1CaCO 3 -10 h sintering with potential corrosion of −1.59 V SCE and corrosion rate of 1.01 mmpy. From the microstructure after electrochemical testing, it was revealed that volcano shaped structure and crack would occur after exposure to Hank’s solution