The conversion from the low‐spin to the high‐spin state in spin‐crossover transition metal complexes leads to bond‐length isomers, since the distance between the metal center and the coordinating ligand atom necessarily increases by 0.04–0.28Å. The coexistence of two such isomers and the effect of temperature and irradiation on their interconversion has been demonstrated by Mössbauer spectroscopy.
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Gütlich et al. (1994) studied this question.
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