Dioxygen adducts of solvent, imidazole and phenolate bound iron porphyrin complexes are reported. The data show that the Fe-O vibration of the Fe-O2 species shifts from 584 cm(-1) to 570 cm(-1) as neutral axial ligands are replaced by the anionic phenolate ligand.
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Das et al. (2013) studied this question.
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