The divalent titanium compounds [(η6‐C6H5Me)Ti(Cl2AlCl2)2] (1) and [(η6‐C6Me6)Ti(Cl2AlCl2)2] (2) are syndiospecific catalysts in the polymerization of styrene when activated with methylaluminoxane. The polystyrene is of exceptionally high molecular weight.
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Kaminsky et al. (1995) studied this question.
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