Oxidative addition of MesNCH–CHNMes (Mes = mesityl) to the aluminium(I) tetramer, [Al(C5Me5)]4, results in the monomeric aluminium(III) derivative, [(η5-C5Me5)AlN(Mes)CHCHN(Mes)], which has been characterised by X-ray crystallography.
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Cowley et al. (1998) studied this question.
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