Controlled Formation of Nickel Oxide Nanoparticles on Mesoporous Silica using Molecular Ni4O4 Clusters as Precursors: Enhanced Catalytic Performance for Dry Reforming of Methane

Supported NiO nanoparticles (NPs) were prepared by impregnation of mesoporous silica SBA‐15 with a molecular, metalorganic [Ni4O4] cubane cluster as precursor. By using this ligand‐stabilized Ni cluster, deposition of four Ni ions in close proximity on the silica support was achieved; this resulted in the formation of small and highly dispersed NiO NPs after heat treatment. These clusters were shown to have a significant influence on the formation of NiO NPs compared to a conventional Ni(OAc)2 precursor. After a further reduction step, the materials were used as catalysts for the dry reforming of methane, which showed that preorganization of the Ni atoms on the support surface had a beneficial effect on the methane conversion rate.