Über die Funktion von Di(tert‐butyl)silandiolat als Anker für Metallfragmente in hohen und mittleren Oxidationsstufen. Synthese und Strukturen von (tBu2SiO2(TeCl2–μ‐Cl2 – TeCl2) und (tBu)2Si(OReO3)2

Function of Di(tert‐butyl)silanediolate as an Anchor for Metal Fragments in High and Medium Oxidation States. Synthesis and Structures of (tBu)2SiO2(TeCl2 – μ‐Cl2 – TeCl2) and (tBu)2Si(OReO3))2 The compounds (tBu)2SiO2(TeCl2 – μ‐Cl2 – TeCl2) (2) and (tBu)2Si(OReO3)2 (3) have been prepared by the reactions of (tBu)2Si(OH)2 (1) with TeCl4 and Re2O7. The single‐crystal X‐ray structures of 2 and 3 are reported. The (tBu)2SiO2 group functions as an anchor for the metal fragments TeCl3 and ReO3.