A photoswitchable arrangement for direct electrochemistry of the redox protein cytochrome c can result from the application of CdSe/ZnS quantum dots on gold electrodes. “On/off” responses can be realized through photoexcitation of the quantum dots. Electrode illumination resulted in stepwise heterogeneous electron transfer from the electrode via the semiconductor particles to the heme proteins (see figure).
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Stoll et al. (2006) studied this question.
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