June 10, 2004Organometallics

Catalytic Isomerization of Cyanoolefins Involved in the Adiponitrile Process. C−CN Bond Cleavage and Structure of the Nickel π-Allyl Cyanide Complex Ni(η 3 -1-Me-C 3 H 4 )(CN)(dppb)

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Abstract

Isomerization of 2-methyl-3-butenenitrile to 3-pentenenitrile is catalyzed by nickel π-allyl cyanide complexes. The mechanism is supported by in situ NMR monitoring and DFT studies.

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Chaumonnot et al. (2004) studied this question.

synapsesocial.com/papers/6aa46edf481326eee3b72b9c https://doi.org/10.1021/om049706i

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Abstract

Isomerization of 2-methyl-3-butenenitrile to 3-pentenenitrile is catalyzed by nickel π-allyl cyanide complexes. The mechanism is supported by in situ NMR monitoring and DFT studies.

Catalytic Isomerization of Cyanoolefins Involved in the Adiponitrile Process. C−CN Bond Cleavage and Structure of the Nickel π-Allyl Cyanide Complex Ni(η 3 -1-Me-C 3 H 4 )(CN)(dppb)

Abstract

Discussion

Cite This Study

Catalytic Isomerization of Cyanoolefins Involved in the Adiponitrile Process. C−CN Bond Cleavage and Structure of the Nickel π-Allyl Cyanide Complex Ni(η 3 -1-Me-C 3 H 4 )(CN)(dppb)

Abstract

Discussion

Cite This Study

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