Ultrasonic-assisted fabrication of thin-film electrochemical detector of H2O2 based on ferrocene-functionalized silver cluster

A novel ferrocene-functionalized silver cluster (FcAgCs) has been designed and synthesized with the assistant of ultrasound treatment and fully characterized by single crystal spectroscopy, IR, UV–Vis, XRD, TGA, NMR, CV and elemental analyses. Ultrasound synthesis method facilitates and accelerates synthesis of this amazing structure and plays a vital role in the synthesis of this special cluster. Single-crystal X-ray analysis reveal that the cluster can be described as a cationic [(dppf) 2 Ag 4 (C C t Bu) 2 (CH 3 OH) 2 ] 2+ (dppf = 1,1′-bis(diphenylphosphino)ferrocene) species consisted of four rhombic silver atom and two isolated BF 4 - counter anions. Thermal stability greater than 200 °C and solution CV results show that the title cluster is sufficiently stable and suitable for the fabricating of FcAgCs/ITO thin-films and exploring as electrochemical responding materials. Based on its properties, we use it to prepare thin-films on ITO substrate by spin coating method. Verification of synthesis, thickness, uniformity and stability of the fabricated FcAgCs/ITO thin-films were characterized and confirmed by UV, XRD, SEM and the scotch tape adhesion peel test. Moreover, we use this FcAgCs/ITO thin-film electrode as thin-film electrochemical detector which shows sensitive and quick response in the detection of H 2 O 2 .