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The interactions of hydrogen cyanide, hydrogen sulphide, toluene thiols, fluorocarboxylic, nitric, and perchloric acids with trans-chlorocarbonylbis(triphenylphosphine)iridium(I), and of some of these molecules with chlorotris(triphenylphosphine)rhodium(I) and other iridium and rhodium complexes, have been studied. The products of oxidative addition, which normally have a metal–hydrogen bond, have been studied by infrared and n.m.r. spectroscopy as well as by chemical techniques.
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Singer et al. (1968) studied this question.
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