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The effects of Na on the electronic structure and electrical properties of {α}-sexithiophene (α6T) are investigated with electron spectroscopic methods under UHV conditions. A shift of the valence-band edge away from the Fermi level, and the evolution of states in the gap, can be determined. In a classical band-structure picture this could be explained as an n-type doping process. However, all results point at a high localization of the negative charge at the sulfur atom which is reflected in a very low specific conductivity.
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Murr et al. (1998) studied this question.
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