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Parallel planes formed by three Ni and three Se atoms are common features of the complexes 2–4 in the crystal. Complex 1 contains a trigonal Ni6 prism with Se atoms lying above each face. Complexes 2–4 consist of face‐sharing Ni6 octahedra with the Se atoms as μ3 and μ4 ligands. equation image
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Fenske et al. (1987) studied this question.
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