Experimental and computational analysis reveals chalcogen bonding in metal–organic frameworks, demonstrating that metal centers govern bond strength and directionality.
The use of chalcogen bonding in the design of building blocks of metal-organic frameworks was demonstrated for the first time by experimental and theoretical methods. The supramolecular mode of the coordinated ligand as well as the chalcogen bond parameters (strengths and directionality) between the tectons are dependent on the metal centres.
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Aliyeva et al. (2025) studied this question.
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