Cyclohexylidene-protected diphosphinite-Rh complex A derived from α,α‘-trehalose was treated with acidic resin in methanol to get the unprotected complex B, which is water soluble. Preparation of complexes A−C and their applications for hydrogenations show the problems and prospects of using water as a solvent for these reactions.
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Shin et al. (1999) studied this question.
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