Electrochemical study reveals cysteine-catalyzed electroreduction of bismuth(III) on liquid film electrodes, indicating electron transfer mediated by active complexes.
The cyclically refreshable liquid silver amalgam film silver based electrode (R-AgLAFE) to study of electrode processes under the “cap-pair” conditions was used. The catalytic effect of cysteine on the Bi(III) ions electroreduction processes has been demonstrated. The magnitude of the catalytic effect is related to the formation of the Bi(III) – Hg(SR)2 active complexes mediating electron transfer equilibrium
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Nosal‐Wiercińska et al. (2022) studied this question.
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