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A previous paper gave the results of a full calculation involving free ion and crystal–field interaction within the 4 f2 and 4 f15d1 configurations. Presently, the calculation is extended to 4 f16s1 and 4 f16p1 as well. As a result, the usual experimental/calculated discrepancy of the 1D2 multiplet is completely eliminated. A complete Hamiltonian, including the magnetic contribution, is utilized to reproduce the Zeeman effect in PrCl3.
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Garcia et al. (1989) studied this question.
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