A Comparative Scanning Tunneling Microscopy Study of Physisorbed Linear Quadrupolar Molecules: C2N2 and CS2 on Au{111} at 4 K

Submonolayer and near-monolayer coverages of cyanogen (C 2 N 2 ) and carbon disulfide (CS 2 ) were independently dosed and studied on Au{111} at 4 K. Low-temperature scanning tunneling microscopy was used to investigate the intermolecular and substrate−adsorbate interactions of each of the two chemical species. Both molecules were found to be weakly physisorbed and to form incommensurate structures with respect to the Au{111} lattice. The superlattice formed by the Au{111} reconstruction was determined to have a pronounced effect on the aggregation of the adsorbates. C 2 N 2 with a high quadrupole moment does not form an ordered structure and is easily moved by the scanning tunneling microscope tip at 4 K. In contrast, CS 2, having a smaller quadrupole moment, forms a molecular herringbone lattice structure. The Au{111} reconstruction also influences the direction of the CS 2 ordered domains, aligning the CS 2 molecular herringbone lattice unit cell in a 3-fold symmetry. These observations are discussed in terms of the current understanding of the dynamics of 2D solid/liquid−gas interfaces.