Good semiconductor properties are exhibited by stable bridged metal complexes containing s-tetrazine as an N-donor ligand. Square-planar metal complexes, for example, phthalocyaninatoruthenium(II) and 2,3-naphthalocyaninatoiron(II), may be bridged. The structure of this hexcoordinated bridged polymer is indicated in formula 1.
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Keppeler et al. (1987) studied this question.
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