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March 11, 2017European Journal of Inorganic Chemistry

Hexadecanuclear Copper Monothiocarbonates: An Emissive Cluster Building Block

Arvind Kumar Gupta Pilli V.V.N. Kishore Jian‐Hong Liao Yuan‐Jang Chen C. W. Liu

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Abstract

A novel CuI cluster, Cu16L16·2CH3COCH3 (1), derived from a cyclohexylmonothiocarbonate ligand (L) was synthesized and structurally characterized. Coordinated‐solvent‐replacement reactions of 1 with various N‐donor ligands to provide 2–5 were demonstrated. Clusters 1–3 and 5 display photoluminescence, whereas 4 is nonemissive. It appears that the emission characteristic of 1 can be tuned by ancillary N‐donor ligands.

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Gupta et al. (2017) studied this question.

synapsesocial.com/papers/6aa50dbca1c24c0d0a0a5d4c https://doi.org/10.1002/ejic.201700070

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