Branched‐regioselective hydroformylation of allylic o‐DPPB esters has been accomplished with mono‐ and disubstituted alkene functions in good to excellent yields and selectivities. Optimized reaction conditions allowed the reaction of even trisubstitued alkenic functions. These reactions occur as a result of a significant rate‐accelerating effect exerted by the catalyst‐directing o‐DPPB group, as exemplified by highly position‐, regio‐, and diastereoselective hydroformylation of the geranyl and neryl o‐DPPB esters.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
No takes yet. Share an insight, caveat, or question.
Breit et al. (2007) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: