A catalyst system based on Pd(OCOCF 3 ) 2 /( S )-binap has been established to effect asymmetric carbonylative cyclization of prochiral o -allylaryl triflates and 2-allylalkenyl triflates with carbon monoxide to produce high yields of enantiomerically enriched cyclopentenones (up to 96% ee).
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Hayashi et al. (1999) studied this question.
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