A two-dimensional fluorescence (excitation/emission) spectrum of C2 produced in an acetylene discharge was used to identify and separate emission bands from the dΠg3←cΣu+3 and dΠg3←aΠu3 excitations. Rotationally resolved excitation spectra of the (4←1), (5←1), (5←2), and (7←3) bands in the dΠg3←cΣu+3 system of C2 were observed by laser-induced fluorescence spectroscopy. The molecular constants of each vibrational level, determined from rotational analysis, were used to calculate the spectroscopic constants of the cΣu+3 state. The principal molecular constants for the cΣu+3 state are Be=1.9319(19)cm−1, αe=0.01855(69)cm−1, ωe=2061.9cm−1, ωexe=14.84cm−1, and T0(c−a)=8662.925(3)cm−1. We report also the first experimental observations of dispersed fluorescence from the dΠg3 state to the cΣu+3 state, namely, dΠg3(v=3)→cΣu+3(v=0,1).
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Joester et al. (2007) studied this question.
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