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The structure factor Sm(Q) for liquid methyl alcohol (CD3OD) at room temperature was obtained by means of the LINAC-TOF neutron diffraction method. An analysis of the diffraction data was carried out, and the molecular structure of CD3OD in liquid phase was determined as: the O–D, C–O, and C–D bond lengths are 0.990±0.010, 1.435±0.005 , and 1.085±0.005 Å, respectively. The O–D and C–D lengths were found to be longer than those values determined in gaseous phase.
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Tanaka et al. (1984) studied this question.
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