Synthesis of inherently dissymmetric polyamides,

The preparation of polyamides from derivatives of optically active biphenic acid is described. The diacid chlorides chosen were 2,2′‐dinitro‐6,6′‐dimethylbiphenyl‐4,4′‐dicarbonyl chloride and 2,2′‐dichloro‐6,6′‐dimethylbiphenyl‐4,4′‐dicarbonyl chloride, the diamines were phenyldiamines (o‐, m‐, p‐) piperazine, trans‐2,5‐dimethylpiperazine, and 1,2‐piperaazolidine. Polymerization was carried out by the method of interfacial polycondensation. The polymers of aromatic diamines were insoluble in common organic solvents but soluble in dimethylformamide containing 5% lithium chloride, triesters of phosphoric acid, and methanesulfonic acid. The polymers of aliphatic diamines were also insoluble in common organic solvents but soluble in trifluoroethanol. All polymers had melting points higher than 280°C.