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The cross‐link density of dicumyl peroxide (DCP) vulcanizates of NR and SBR has been determined by the equilibrium swelling method. From a plot of elastically effective cross‐links corrected for chain ends against the moles of DCP decomposed, the efficiency of crosslinking has been found. The values of g in the FLORY equation have been calculated at varying densities of cross‐links, and it has been found that both the FLORY equation as well as other equations relating chemical cross‐links to physical ones can be satisfactorily empolyed for the calculation of chemical cross‐links from the physical cross‐links determined by swelling measurement.
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Manik et al. (1969) studied this question.
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