Nitrogen in the gate oxide of a 3.3-V, 0.4-μm CMOS technology was modulated in a variety of ways, including treatments with N2O, NO, oxidation at elevated pressure, and post-oxidation annealing. A direct correlation was observed between the fixed positive charge and the hot-electron immunity, regardless of the means by which the nitrogen was incorporated, or subsequently annealed. The implication is that one benefit and one drawback of nitrided-oxide gate oxides are inextricably linked, with significant effects on the transistor design.
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Hook et al. (1997) studied this question.
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