An optically-active redox amino acid, l-ferrocenylalanine was synthesized. The amino acid was incorporated into polypeptides in the form of a single l-ferrocenylalanine unit or a l-ferrocenylalanyl-l-ferrocenylalanine unit. Those polypeptides showed reversible redox property on the cyclic voltammetry.
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Kira et al. (1997) studied this question.
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