Irradiation of difluorodiiodomethane 1 with pyrroles, indole and imidazoles in dimethylformamide gives the Corresponding trifluoromethylated products, whereas irradiation with enamines results in 2-trifluoromethyl ketones. A photoinduced electron-transfer mechanism is proposed.
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Chen et al. (1993) studied this question.
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