Dehydrogenation of Amine–Boranes Using p‐Block Compounds

Amine-boranes have gained a lot of attention due to their potential as hydrogen storage materials and their capacity to act as precursors for transfer hydrogenation. Therefore, a lot of effort has gone into the development of suitable transition- and main-group metal catalysts for the dehydrogenation of amine-boranes. During the past decade, new systems started to emerge solely based on p-block elements that promote the dehydrogenation of amine-boranes through hydrogen-transfer reactions, polymerization initiation, and main-group catalysis. In this review, we highlight the development of these p-block based systems for stoichiometric and catalytic amine-borane dehydrogenation and discuss the underlying mechanisms.