Dinuclear zinc(II) complexes have been prepared from one non-symmetric and two symmetric compartmental ligands in which the pendant arms, bearing pyridyl and phenolic functions, are bridged by spacers derived from 1,n-diaminoalcohols. The X-ray crystal structures of four complexes [Zn2L1(OAc)](ClO4)2·CH3OH (1a), [Zn2L1(OAc)](BPh4)2·6H2O (2a), [Zn2L2(OAc)](PF6)2 (4a) and [Zn2L3(OAc)] ·2.5H2O·1.5CH3OH (8a) are reported.
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Adams et al. (2002) studied this question.
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