The synthesis of a mesoporous poly(ionic liquid) network via a hard-templating pathway is presented. Structure analysis was carried out using gas adsorption, small-angle X-ray scattering, and electron microscopy. The mesoporous poly(ionic liquid) showed a significantly faster CO 2 adsorption than its nonporous counterpart. We found the adsorption is accompanied by strong interactions, which are also reflected in a high CO 2 over N 2 selectivity.
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Wilke et al. (2012) studied this question.
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