A direct and convenient procedure for the solvent‐free mechanochemical aminochlorination of electron‐deficient olefins promoted by (diacetoxyiodo)benzene [PhI(OAc)2] was described using commercially available and cheap chloramine‐T as a nitrogen and chlorine source. The vicinal chloramine derivatives were obtained in high regio‐ and stereoselectivity with good yields. PhI(OAc)2 was superior to metal salts for the aminochlorination of electron‐deficient olefins.
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Wang et al. (2007) studied this question.
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