A trinucleating cyclophane bearing three β-diketimine arms, and the corresponding iron(II) and manganese(II) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N2Br2 donor set, in which a unique combination of μ(3), μ, and terminal coordination modes are observed for the halide donors.
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Guillet et al. (2013) studied this question.
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