Apatite-type La(9.33)(SiO(4))(6)O(2) hollow nanoshells were successfully synthesized by a controlled route. These oxide-ion-conducting hollow nanoshells were used to catalyze oxidative coupling of methane, and an enhanced catalytic performance at relatively low temperature was realized. The high-activity and energy-saving features were attributed to their hollow nanostructures and oxide ion conductivity.
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Zhang et al. (2010) studied this question.
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