The Diels–Alder reactions of difluoro(methylene)cyclopropanes (F2MCPs) with cyclic dienes are described. These cycloaddition reactions exhibited complete regioselectivity and high endo‐stereoselectivity. The obtained cycloadducts underwent a retro‐Diels–Alder reaction to give the original dienophiles and dienes when heated, reflecting the reversible Diels–Alder reactivity of F2MCPs.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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Hang et al. (2007) studied this question.
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