Alternating-gradient focusing and deceleration of large molecules

We have focused and decelerated benzonitrile (C₇H₅N) molecules from a molecular beam, using an array of time-varying inhomogeneous electric fields in alternating-gradient configuration. Benzonitrile is prototypical for large asymmetric top molecules that exhibit rich rotational structure and a high density of states. At the rotational temperature of 3.50.3em0exK in the pulsed molecular beam, many rotational states are populated. Benzonitrile molecules in their absolute ground state are decelerated from 3200.3em0exto0.3em0ex2890.3em0exm∕s, and similar changes in velocity are obtained for excited rotational states. All measurements agree well with the outcome of trajectory calculations. These experiments demonstrate that such large polyatomic molecules are amenable to the powerful method of Stark deceleration.