A series of complexes having the general formulas [TpM(NO)(L)Br] and [TpmM(NO)(L)Br]BF 4 (M = Mo or W and L = a moderate σ-donor) have been prepared. Variations in L provide access to M(I) complexes having a broad range of electronic and steric properties. Reduction of a limited number of these complexes in the presence of aromatic molecules produces novel complexes with the general formula [TpM(NO)(L)(η 2 -aromatic)] n + ( n = 0, 1).
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Ha et al. (2006) studied this question.
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