Reduction of lunar basalt 70035: Oxygen yield and reaction product analysis

Oxygen production from a lunar rock has been experimentally demonstrated for the first time. A 10 g sample of high‐Ti basalt 70035 was reduced with hydrogen in seven experiments at temperatures of 900–1050°C and pressures of 14.7–150 psia. In all experiments, water evolution began almost immediately and was essentially complete in tens of minutes. Oxygen yields ranged from 2.93 to 4.61% of the starting sample weight, and showed weak dependence on temperature and pressure. Analysis of the solid samples demonstrated total reduction of Fe2+ in ilmenite and small degrees of reduction in olivine and pyroxene. TiO2 was also partially reduced to one or more suboxides. Data from these experiments provide a basis for predicting the yield of oxygen from lunar basalt as well as new constraints on natural reduction in the lunar regolith.