Study of polymer treatment with tetrafluoromethane plasma: Reactivity of fluorinated species on model surfaces

Polyolefins and their model molecules, some n‐alcanes, have been modified by a tetrafluoromethane microwave plasma. The chosen molecules are high‐density polyethylene (HDPE) and hexatriacontane (HTC), low‐density polyethylene (LDPE) and paraffin, and polycaprolactone (PCL) and octadecyl octadecanoate (ODO). It has been found, except for paraffin, that the model surfaces have the same behavior as the corresponding polymers. Plasma modification is described as the sum of two mechanisms: degradation and fluorination. These reactions seem to be competitive and parallel. Degradation and fluorination rates are dependent on treatment time and are practically independent on substrate position. A domain of fluorination exists near the edge of plasma, whatever the substrate in or outside plasma.