The polymerization of octadecyl methacrylate (2) and of 3‐methylenepentamethylene triacrylate [trimethylolpropane triacrylate (1)], induced by a microwave plasma and the chemical structure of the final polymers are described. Modification of the polymers by cold plasma (CF4) treatment is pointed out. The extent of fluorination is not proportional to the time of treatment. A maximum is observed which is due to the evolution of the concentration of different excited species, such as F*, CF* and CF*, present in the gas phase.
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Poncin‐Epaillard et al. (1990) studied this question.
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