NCP pincer palladacycle 1 has been reported as an excellent catalyst precursor for the Suzuki–Miyaura reaction. Now, it’s properties have been evaluated in the Heck reaction. 1 is highly active for the coupling of ArI, ArBr and electron-poor ArCl with n-butyl acrylate showing limitations in the reaction of deactivated ArCl and sterically hindered olefins.
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Rosa et al. (2012) studied this question.
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