The microbial transformation of vindoline (1) by Aspergillus niger, Fusarium lini and F. monolinum afforded 17-deacetylvindoline (2) as the sole metabolic product, whereas α-santonin (3) was regiospecifically reduced to 1,2-dihydro-α-santonin (4) by Aspergillus niger.
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Rahman et al. (1998) studied this question.
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