A method for the synthesis of phenylphosphonic acid functionalized poly[aryloxyphosphazenes] is described. Diphenyl chlorophosphate was used as the phosphonating agent and was allowed to react with lithio-functionalized aryloxyphosphazenes, followed by treatment with aqueous sodium hydroxide. Subsequent acidification with aqueous hydrochloric acid yielded phenylphosphonic acid functionalized poly[aryloxyphosphazenes]. These polymers are candidates for use as proton-conducting membranes in fuel cells.
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Allcock et al. (2002) studied this question.
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