Crystalline ethylzinc chloride exists as a coordination polymer in the form of puckered sheets with Zn 3 Cl 3 rings, which differ from the well-known structure of [EtZnI] ∞ in adopting a boat rather than chair conformation. This contrasts with the tetrameric cubane structure suggested in 1966 based on molecular weight determinations in benzene solution.
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Guerrero et al. (2006) studied this question.
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